If it is a hissing noise, or hissing and "bubbling", it is completely normal. The refrigerant has to equalize between the "Low" and "High" sides of the system. This will typically make hissing sounds. During operation you can see 30 PSI Low and 280 PSI high. Without the system running it typically sits around 80 PSI on both. My dad's old Caravan, my Civic, and my house A/C do it as well. Don't hear though on our German cars as they have more sound deadening.
2012 Mercedes-Benz GLK350 4Matic
2009 Smart ForTwo "Passion"